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Boris Derjaguin

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Boris Derjaguin
Born
Boris Vladimirovich Derjaguin

(1902-08-09)9 August 1902
Moscow, Russian Empire
Died16 May 1994(1994-05-16) (aged 91)
Moscow, Russian Federation
Known forDerjaguin approximation
DLVO theory
DMT model
Diffusiophoresis
Disjoining pressure
Polywater
AwardsUSSR State Prize (1990)
Scientific career
FieldsBiophysics
Physical chemistry

Boris Vladimirovich Derjaguin (or Deryagin; Russian: Бори́с Влади́мирович Деря́гин) (9 August 1902 in Moscow – 16 May 1994) was a Soviet and Russian chemist. He laid the foundation of the modern science of colloids and surfaces; an epoch in the development of the physical chemistry of colloids and surfaces is associated with his name. He was elected to the Russian Academy of Sciences,

Derjaguin became famous in scientific circles for his work on the stability of colloids and thin films of liquids which is now known as the DLVO theory, after the initials of its authors: Derjaguin, Landau, Verwey, and Overbeek. It is universally included in text books on colloid chemistry and is still widely applied in modern studies of interparticle forces in colloids. In particular, the Derjaguin approximation is widely used in order to approximate the interaction between curved surfaces from a knowledge of the interaction for planar ones.

Derjaguin was also briefly involved in polywater research during the 1960s and early 1970s. This field claimed that if water was heated then cooled in quartz capillaries, it took on astonishing new properties. Eventually, the scientists who were involved in polywater admitted it did not exist, claiming they were misled by poorly designed experiments (Derjaguin rejected polywater in 1973[1]).

He is also known for having hotly rejected[2] some of the then-new ideas of adhesion as presented by the Western bloc[3] in the 1970s. His model came to be known as the DMT (after Derjaguin, Muller and Toporov) model,[3] while the model presented by Western bloc scientists came to be known as the JKR (after Johnson, Kendall and Roberts)[4] model for adhesive elastic contact. This rejection proved to be instrumental in the development of the D. Tabor[5][6] and later D. Maugis[2][7] parameters that quantify which contact model (of the JKR and DMT models) represent adhesive contact better for specific materials.

In 1935, Derjaguin founded the Laboratory of Thin Layers at the Institute of Physical Chemistry of the Academy of Sciences of the Soviet Union in Moscow. He was the head of the laboratory until 1988, when the age limit for directors of research divisions was introduced. He was replaced by Vladimir Muller as the head of the laboratory.[8]

Selected works

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From 1980 onwards

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  • Derjaguin, B. V. (1980). "Analytical calculation of repulsion forces arising when the non-ionic diffuse adsorption layers are overlapped". Colloid and Polymer Science. 258 (4): 433–438. doi:10.1007/BF01480837.
  • —— (1980). "Structural and thermodynamic peculiarities of the boundary layers of liquids". Pure and Applied Chemistry. 52 (5): 1163–1178. doi:10.1351/pac198052051163.
  • —— (1982). "Certain results obtained in research on long-range surface forces". Russian Chemical Bulletin. 31 (8): 1528–1532. doi:10.1007/BF00956886. S2CID 95538345.
  • —— (1987). "Modern state of the investigation of long-range surface forces". Langmuir. 3 (5): 601–606. doi:10.1021/la00077a001.
  • —— (1987). "Some results from 50 years' research on surface forces". Surface Forces and Surfactant Systems. Progress in Colloid & Polymer Science. Vol. 74. Steinkopff Verlag. pp. 17–30. doi:10.1007/BFb0109369. ISBN 978-3-7985-0745-6.
  • —— (1988). "Mechanical properties of the boundary lubrication layer". Wear. 128 (1): 19–27. doi:10.1016/0043-1648(88)90250-5.
  • —— (1989). "The influence of surface forces on the formation of structural peculiarities in the boundary layers of liquids and boundary phases". Colloids and Surfaces. 38 (1): 49–60. doi:10.1016/0166-6622(89)80142-8. S2CID 95738552.
  • —— (1989). Theory of Stability of Colloids and Thin Films. Plenum Press. ISBN 978-0-306-11022-1. OCLC 18959853. OL 10322147M.
  • —— (1992). "On the question of development of the thermodynamics of the systems with thin (non-gibbsian) interlayers: Methods for determination of the thermodynamic thickness of thin interlayers". Advances in Colloid and Interface Science. 40: 191–200. doi:10.1016/0001-8686(92)80076-A.
  • —— (1992). "Summary of development of the theory of stability of colloids and thin films". Russian Chemical Bulletin. 41 (8): 1321–1328. doi:10.1007/BF00864326. S2CID 98301174.
  • —— (1993). "Amendment of Archimedes' principle". Colloids and Surfaces A: Physicochemical and Engineering Aspects. 81: 289–290. doi:10.1016/0927-7757(93)80257-F.
  • Derjaguin, B. V. (1993). "The world of neglected thicknesses and its place and role in nature and technology". Colloids and Surfaces A: Physicochemical and Engineering Aspects. 79 (1): 1–9. doi:10.1016/0927-7757(93)80154-7.

Reprints

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See also

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References

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  1. ^ Derjaguin, B. V.; Churaev, N. V. (1973). "Nature of "anomalous water"". Nature. 244 (5416): 430–431. Bibcode:1973Natur.244..430D. doi:10.1038/244430a0. S2CID 4293924.
  2. ^ a b D. Maugis, Contact, Adhesion and Rupture of Elastic Solids, Springer-Verlag, Solid-State Sciences, Berlin 2000, ISBN 3-540-66113-1
  3. ^ a b B. V. Derjaguin, V. M. Muller and Y. P. Toporov, "Effect of contact deformations on the adhesion of particles", J. Colloid Interface Sci. 53 (1975), pp. 314-325
  4. ^ K. L. Johnson, K. Kendall and A. D. Roberts, "Surface energy and the contact of elastic solids", Proc. R. Soc. Lond. A 324 (1971), pp. 301-313
  5. ^ D. Tabor, "The hardness of solids", Rev. Phys. Technol. 1 (1970), pp. 145-179
  6. ^ D. Tabor, "Surface forces and surface interactions", J. Colloid Interface Sci. 58 (1977), pp. 2-13
  7. ^ D. Maugis, "Adhesion of spheres: The JKR-DMT transition using a Dugdale model", J. Colloid Interface Sci. 150 (1992), pp. 243-269
  8. ^ Бойнович, Л. Б.; Емельяненко, А. М. (2020). "Развитие учения о поверхностных силах – от концепции расклинивающего давления к современным нанотехнологиям" (PDF). Журнал физической химии (in Russian). 94 (3): 371–378.
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